Cyanide Half-Cell Ion Selective Electrode (ISE)

HI4009

Cyanide Half-Cell Ion Selective Electrode (ISE)

$779.99

The HI4009 is a solid state, half-cell ion selective electrode (ISE) for the determination of cyanide (CN-) in solution. The silver halide sensing pellet produces a potential change due to the cyanide ion exchange between the inorganic pellet membrane and the sample. The internal sensing elements are housed within a durable epoxy body. The HI4009 is ideal for a variety of applications in plating, wastewater, and agriculture.

Solid state sensor
Detection from 0.026 to 260 mg/L CN-
For use with HI5315 reference half-cell

Learn More

Thank you for your interest in our products. A representative will contact you within the next business day.

The HI4009 cyanide selective electrode is a potentiometric half-cell sensor housed within an epoxy body. The internal elements are isolated from the sample by a compressed silver halide sensing membrane. This solid-state sensor requires a separate reference electrode to complete the measurement system.

Hanna’s solid-state half-cell ISEs are designed for use with the HI5315 reference half-cell. The reference half-cell features a cone style junction. The skirted cone geometry of the reference forms the liquid junction with the test solution at the tip of the junction cone, producing a highly stable reference potential and consistent flow rates of electrolyte into the solution. A simple press of the top portion of the ISE makes it easy to empty the electrolyte fill solution and replace when necessary.

For the HI4009 to measure cyanide accurately, it is important that the ionic strength of the standards and sample be adjusted to a high and constant value with the cyanide ionic strength adjuster (ISA) solution. The alkaline ISA ensures that the activity coefficient is constant so the concentration of free cyanide ions can be measured. Measuring all solutions with a constant ionic strength reduces the margin of error between measurements. The HI4009 cyanide solid-state ISE can measure from 1µM (0.026 mg/L) to 0.01M (260 mg/L).

Conversion Table for CN^-

	Multiply
moles/L (M) to ppm (mg/L)	2.602 x 10⁴
ppm (mg/L) to M (moles/L)	3.843 x 10^-5

Features at-a-glance

Fixed Sensing Modules

Solid-state half-cell ISEs are electrodes that detect free ions in a solution. The highly insoluble, compressed sensing pellet is attached to the HI4009 cyanide half-cell by a fixed sensing module for ease of use.

Durable Epoxy Body

The probe body of the cyanide half-cell ISE is composed of durable epoxy resin.

BNC Connection

The HI4009 has a universal BNC connector for easy connection to any benchtop meter with a female BNC probe input.

Theory of Operation

A solid-state sensor electrode develops a voltage due to the ion exchange that occurs between the solution and the inorganic membrane. An equilibrium occurs due to the highly limited solubility of the membrane material in the sample. When the ionic strength of the solution is fixed by the addition of ISA, the voltage is proportional to the concentration of free ions in solution.

Resources

Specifications

Specification Name	Detail
SKU	HI4009
Type	solid-state; half-cell
Measurement Range	0.01M to 1•10-6M 260 to 0.02 mg/L (ppm)
Optimum pH Range	>11
Temperature Range	0 to 80°C
Diameter	12 mm
Length	120 mm
Body Material	epoxy
Cable	1 m coaxial
Common Applications	determination of free cyanide ions in plating baths, waste water and in plant and soil samples
Connection	BNC
Warranty	6 months

Manuals

Manual Download